Manufacturing Technology 2025, 25(6):735-741 | DOI: 10.21062/mft.2025.083

Characterization of microstructure and defects in the Ti-6Al-4V alloy produced by 3D printing SLM technology

Kateřina Caldová ORCID...1, Andrea Školáková ORCID...1,2, Jan Pinc ORCID...1,2, Dalibor Vojtěch ORCID...1
1 Department of Metals and Corrosion Engineering, University of Chemistry and Technology, Prague, Technická 5, 166 28 Prague 6, Czech Republic
2 FZU – The Institute of Physics of the Czech Academy of Sciences, Na Slovance 1999/2, Prague 8, 182 21, Czech Republic

The Ti-6Al-4V alloy is widely used as a material for medical implants. In the future, it may be employed for 3D printing using the selective laser melting method. The advantages of 3D printing are for example production of complex shapes or ability to create customized implants. One of the disadvantages of this method is the deterioration of mechanical properties, particularly the ductility of the alloy, caused by high residual stress resulting from rapid cooling during printing. This article aims to characterize the microstructure and defects of the printed alloy and the impact of hot isostatic pressing. Optical microscopy, scanning electron microscopy, and micro-computed tomography were utilized for the study. It was found that the heat treatment has a significant effect on the pore size and microstructural transformation. These findings could lead to the optimization of the manufacturing process and improve the quality of implants made from this alloy.

Keywords: Selective laser melting (SLM), Ti-6Al-4V alloy, Defects, Pores, Hot isostatic pressing (HIP)
Grants and funding:

CzechNanoLab project LM2023051 funded by MEYS CR is gratefully acknowledged for the financial support of the measurements/sample fabrication at LNSM Research Infrastructure. The authors would like to thank the Ministry of Health of the Czech Republic (Project No. NW25-08-00044) and specific university research (A1_FCHT_2025_011) for financial support

Received: August 5, 2025; Revised: December 11, 2025; Accepted: December 15, 2025; Prepublished online: December 18, 2025; Published: December 23, 2025  Show citation

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Caldová K, Školáková A, Pinc J, Vojtěch D. Characterization of microstructure and defects in the Ti-6Al-4V alloy produced by 3D printing SLM technology. Manufacturing Technology. 2025;25(6):735-741. doi: 10.21062/mft.2025.083.
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References

  1. ABD-ELAZIEM, W., et al. (2024). Titanium-Based alloys and composites for orthopedic implants Appli-cations: A comprehensive review. Materials & Design, Vol. 241, pp. 112850. ISSN: [0264-1275]. Go to original source...
  2. WAGNER, W.R., et al. (2020). Biomaterials Science An Introduction to Materials in Medicine, ISBN: [978-0-12-816137-1].
  3. KRIŠTOFOVÁ P, KUBÁSEK J, VOJTĚCH D, PALOUŠEK D, SUCHÝ J. (2019). Microstructure of the Mg-4Y-3RE-Zr (WE43) Magnesium Alloy Produced by 3D Printing. Manufacturing Technology, Vol. pp. 89-94. ISSN [1213-2489]. Go to original source...
  4. ESHAWISH, N., MALINOV, S., SHA, W. et al (2021). Microstructure and Mechanical Properties of Ti-6Al-4V Manufactured by Selective Laser Melting after Stress Relieving, Hot Isostatic Pressing Treatment, and Post-Heat Treatment. J. of Materi Eng and Perform, Vol. 30, pp. 5290-5296 ISSN: [1544-1024]. Go to original source...
  5. WEN, C. (2021). Structural Biomaterials Properties, Characteristics, and Selection, ISBN: [978-0-12-818831-6].
  6. MARIN, E. AND A. LANZUTTI (2023). Biomedical Applications of Titanium Alloys: A Comprehensive Review. Materials, Vol. 17, Basel, Switzerland. ISSN: [1996-1944] Go to original source...
  7. NGUYEN, H.D., et al. (2022). A critical review on additive manufacturing of Ti-6Al-4V alloy: micro-structure and mechanical properties. Journal of Materials Research and Technology, Vol. 18, pp. 4641-4661. ISSN: [2238-7854]. Go to original source...
  8. NGO, T.D., et al. (2018). Additive manufacturing (3D printing): A review of materials, methods, applica-tions and challenges. Composites Part B: Engineering, Vol. 143, pp. 172-196. ISSN: [1359-8368]. Go to original source...
  9. AIZA, I., et al. (2025). Effects of build orientation and inclined features on physical, microstructural and mechanical properties of powder bed fusion additively manufactured metallic parts. Progress in Materials Science, Vol. 147, pp. 101357. ISSN: [0079-6425]. Go to original source...
  10. SONG, Y., et al. (2024). An overview of selective laser sintering 3D printing technology for biomedical and sports device applications: Processes, materials, and applications. Optics & Laser Technology, Vol. 171, pp. 110459. ISSN: [0030-3992]. Go to original source...
  11. HORKÝ R, KUŚMIERCZAK S, NÁPRSTKOVÁ N, KAMBAROVÁ I. (2024). Effect of Heat Treatment and Corrosion Load on the Microstructure of the Ti6Al4V Alloy. Manufacturing Technology, Vol. 24(6) pp. 914-928. ISSN [1213-2489]. Go to original source...
  12. YADROITSEV, I. AND I. YADROITSAVA (2021). 3 - A step-by-step guide to the L-PBF process. In: Fundamentals of Laser Powder Bed Fusion of Metals, pp. 39-77. Elsevier. ISBN: [978-0-12-824090-8]. Go to original source...
  13. DU PLESSIS, A. (2121 6 - Porosity in laser powder bed fusion. In: Fundamentals of Laser Powder Bed Fusion of Metals, pp. 155-178. Elsevier. ISBN: [978-0-12-824090-8]. Go to original source...
  14. SINGLA, A.K., et al. (2021). Selective laser melting of Ti6Al4V alloy: Process parameters, defects and post-treatments. Journal of Manufacturing Processes, Vol. 64, pp. 161-187. ISSN: [1526-6125]. Go to original source...
  15. WANG, S., et al. (2022) Role of porosity defects in metal 3D printing: Formation mechanisms, impacts on properties and mitigation strategies. Materials Today, Vol. 59, pp. 133-160. ISSN: [1369-7021]. Go to original source...
  16. BAGHERIFARD, S. AND M. GUAGLIANO (2021). 12 - Post-processing, In: Fundamentals of Laser Powder Bed Fusion of Metals, pp. 327-348. Elsevier. ISBN: [978-0-12-824090-8]. Go to original source...
  17. GOSTICK, J., et al. (2016). OpenPNM: A Pore Network Modeling Package. Computing in Science & Engineering, Vol. 18, pp. 1-1. ISSN: [1521-9615] Go to original source...
  18. LI, H., et al. (2025). Evaluation of the microstructure and mechanical properties of additive manufactured Ti-6Al-4V alloy under various heat treatment conditions: Optimization of heat treatment programme and depth of effective layer. Journal of Alloys and Compounds, Vol. 1026, pp. 180427. ISSN: [0925-8388]. Go to original source...
  19. SALLICA-LEVA, E., et al. (2016). Ductility improvement due to martensite α' decomposition in porous Ti-6Al-4V parts produced by selective laser melting for orthopedic implants. Journal of the Mechanical Behavior of Biomedical Materials, Vol. 54, pp. 149-158. ISSN: [1751-6161]. Go to original source...
  20. LI, J., et al. (2025). Evolution and prediction of lack of fusion pores in laser powder bed fusion process based on in-situ monitoring. Measurement, Vol. 245, pp. 116617. ISSN: [0263-2241]. Go to original source...
  21. TAO, P.; ZHONG, J.; LI, H.; HU, Q.; GONG, S.; XU, Q (2019), Microstructure, Mechanical Proper-ties, and Constitutive Models for Ti-6Al-4V Alloy Fabricated by Selective Laser Melting (SLM). Metals, Vol. 9, pp. 447. ISSN: [2075-4701] Go to original source...

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